How to produce Metal Oxide Varistor (MOV) for Surge Protection Device (SPD)

How to Produce Metal Oxide Varistor (MOV) for Surge Protection Device (SPD)?

Created by: Glen Zhu | Updated Date: January 9th, 2025

How to Produce Metal Oxide Varistor (MOV) for SPD?

Raw Materials

The core material of MOV is metal oxide powder, especially zinc oxide (ZnO), usually mixed with other metal oxides such as manganese (Mn), iron (Fe), nickel (Ni) in certain proportions to form composite materials with specific electrical characteristics. In addition to metal oxides, other auxiliary materials include:

Binder: Used to bond the powder together before sintering.

Conductive materials: such as silver (Ag) or copper (Cu), used for the production of subsequent electrodes.

Production Process

Granulation

Powder mixing: Zinc oxide and other metal oxides are uniformly mixed in specific proportions through methods such as ball milling and mechanical mixing. This process requires ensuring uniform powder particle size and consistent distribution.

Add binder: In order to ensure the moldability of the material, a certain amount of binder or adhesive (such as polyvinyl alcohol) is usually added, and then continue mixing until a paste with moderate viscosity is obtained.

Measurement and testing:

1. Random sampling for powder inspection.

Molded

Mold pressing: Put the mixed powder material into the mold, and press it into the desired shape through high pressure (usually 10-50 MPa). Common shapes include disc-shaped, cylindrical, sheet-like, etc.

Molding density control: In order to ensure the performance of the varistor, it is necessary to accurately control the density during the molding process to avoid loose or tight particle accumulation.

Measurement and testing:

1. Extract 10 pieces for visual inspection once per hour.
2. Test 6 pieces in each batch for lightning strike testing.

Defecation

Mainly used to remove the binder added in the raw material preparation stage. The role of the binder is to help the raw materials maintain their shape during pressing and forming, but it needs to be removed during sintering process to ensure the electrical and mechanical properties of the final product.

Measurement and testing:

1. All products undergo continuous visual inspection to confirm if there are any defects in the MOV.

Scheduling

After the pressure-sensitive resistor is degassed, it is neatly placed in the box.

The role of the box: by absorbing a certain amount of heat, help the pressure-sensitive resistor to be evenly heated, avoiding cracks caused by too fast or too slow temperature changes.

Measurement and testing:

1. All products are continuously visually inspected to confirm that the products and packaging are free from damage, debris, or any other visual defects.

Sintering

The sintering process of MOV usually occurs under the composite reaction of zinc oxide and other additives. Zinc oxide reacts with other metal oxides at high temperatures, forming specific crystal phase structures and creating a stable ceramic structure. This process enhances the bonding strength between particles, thereby improving the mechanical strength and stability of varistor resistors.

Sintering temperature: Usually between 900°C and 1100°C, the specific temperature depends on the type of metal oxide used.

Sintering time: Typically takes 1 to 4 hours, during which powder particles will diffuse and recrystallize, enhancing material stability and resistivity characteristics.

Measurement and testing:

1. Each batch is randomly selected to confirm that there are no defects or adhesions on the appearance.

Black Disk Cleaning

After sintering, the MOV needs to be slowly cooled to avoid cracks or deformation caused by rapid cooling. After cooling, the surface of the MOV is usually treated in some way:

Removal of surface impurities: If there are impurities such as dust or oil stains during the sintering process, they need to be removed mechanically (such as grinding or wiping).

Surface smoothing treatment: In order to increase the adhesion of subsequent electrodes, the surface may undergo fine polishing or chemical treatment.

Measurement and testing:

1. All products undergo continuous visual inspection to confirm that they are free of defects, cracks, fractures, and severe distortion.

Silver Coating

Coat the sintered MOV surface with a layer of silver paste (Ag) to form an electrical connection.

Use a screen to brush the silver paste on one side of the MOV, commonly in circular or rectangular electrode shapes, ensuring reliable connection between the MOV and external circuit. After heating and drying, cool down and repeat the process by brushing silver paste on the other side before another round of drying treatment.

Measurement and testing:

1. First inspection, extract 10 pieces, check the size specifications of the silver sheet.
2. Randomly select 10 pieces, visually inspect, confirm that the product has clear margins and edge lines, no double-layer misalignment, uniform silver layer color, no serious mixed colors, stains, scratches, silver stacking, overturning edges , cracking or leakage phenomena.
3. Before each batch is put into production, extract 20 pieces for electrical testing using a TTK MOV-168EP tester.
4. Before each batch is put into production, extract 6 pieces for impact testing using an impact generator.
5. Before each batch is put into production,extract 10 pieces for thermal stability testing.

Silver Reduction

After the MOV surface is coated with silver, in the reduction furnace, during the reduction process, silver ions will gradually be reduced to metallic silver and deposited on the coating surface, filling the gaps between silver powder particles, reducing silver ions to metallic silver, thereby enhancing the density, adhesion and conductivity of the silver layer.

Measurement and testing:

1. All products undergo continuous visual inspection to confirm that the product margins and edges are clear, without double layer misalignment, with uniform silver color, no serious mixed colors, stains, scratches, silver stacking, overturned edges, or cracking phenomena.
2. Three samples are taken from each batch for adhesion testing.

Electric Sorting

After restoring all the silver, visually inspect and test with TTK MOV-168EP tester, then randomly select 6 pieces for lightning surge generator testing.

Measurement and testing:

1. All products undergo continuous visual inspection to confirm that the product margins and edges are clear, the silver layer is smooth and uniform in color, without serious mixed colors, stains, scratches, accumulation, overturning edges, cracking or defects.
2. All products undergo continuous testing with TTK MOV-168EP tester to confirm the qualified leakage current and voltage of MOV.

Painting

After the electrical sorting, the MOV is painted and cured in a reflow oven.

This process can only be completed manually, painting is to ensure that the MOV has good waterproof, moisture-proof, and insulating performance.

Measurement and testing:

1. All products undergo continuous visual inspection to confirm that there are no defects such as thin or thick paint on the surface.

Solder Paste

Place the MOV on the dispenser, apply solder paste for better welding of metal electrodes.

Measurement and testing:

1. All products undergo continuous visual inspection to confirm that there are no tin plating, empty soldering, glue breakage, or insufficient adhesive.

Insert Plate

Use a long tail clip to clamp the MOV and electrode together, fixing the electrode, soldering, and MOV.

Measurement and testing:

1. All products undergo continuous visual inspection to confirm that there is no tilting or damage to the black porcelain pieces.

Solder

Solder the clipped MOV through a reflow soldering oven.

Measurement and testing:

1. All products undergo continuous visual inspection to confirm that they are full and firm, with a bright copper surface, no tin hanging on the edges, no stacked tin on original parts, and no tin slag or tin tumors.
2. Three samples are taken from each batch for adhesion testing.

Clean

Clean MOV debris through ultrasonic cleaning machine and oven drying to ensure no solder flux, tin ash, or other debris on the MOV.

Measurement and testing:

1. All products undergo continuous visual inspection to confirm the absence of flux, tin ash, impurities, etc. on the product.

Coating (Packaging, Sealing)

Wrap the electrode feet of MOV with decorative paper tape, apply adhesive to the protrusions, and arrange them neatly on the coating rack.

Preheat the MOV in an oven, pass it through a coating machine to spray powder onto the MOV, then bake in an oven to smooth out the surface of the MOV.

Measurement and testing:

1. All products undergo continuous visual inspection to ensure that the appearance of the product is complete and free from defects such as pinholes, exposed porcelain, sharp peaks, coating gradients, exposed tin, and sealing lumps.
2. 10 samples are taken from each batch for package size measurement.

Packaging

Gumming

Prehea

Coating

Solidification

After the sprayed MOV is sent into the curing furnace, the surface encapsulation of the MOV is cured by high temperature.

Measurement and testing:

1. All products are continuously visually inspected to ensure that the appearance of the product is complete and free from pinholes, exposed porcelain, sharp peaks, coating gradients, exposed tin, encapsulated tumors and other defects.

Dielectric Testing

Perform performance testing on the cured MOV using a TTK MOV-168EP tester.

Measurement and testing:

1. All products undergo electrical performance testing.

Laser Marking

Print logo, model number, and date on the MOV.

Measurement and testing:
1. All products undergo continuous visual inspection to confirm that there are no missing words, unclear text, misprints, or other issues.

Appearance Inspection

Remove excess packaging and electrodes.

Measurement and testing:

1. All products undergo continuous visual inspection to ensure the integrity of their appearance.

OQC Inspection

Each batch of MOV samples undergo testing.

Testing equipment:

1. Impulse generator (10/350µs 60 kA, 8/20µs 160 kA, combination wave of 8/20µs and 1.2/50µs, square wave of 2ms (3000 A))
2. High temperature electric aging equipment
3. TTK MOV-168EP tester

4. Programmable constant temperature and humidity test chamber

5. Rapid temperature change test chamber

Measurement and testing:

1. Each batch sampling inspection, observe appearance, measure dimensions, and test electrical performance through TTK tester.

OQC inspection with Impulse generator

OQC inspection with High temperature electric aging equipment

OQC inspection with TTK MOV-168EP tester

OQC inspection with temperature and humidity test chamber

OQC inspection with Rapid temperature change test chamber

OQC inspection with ICTS 2ms-3 TEST System

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